Influence of Y~(3+),Yb~(3+),Gd~(3+) cations on structural and electromagnetic properties of CuFe_2O_4 nanoferrites prepared via one step sol-gel method

Rare earths(REs) play a key role in distorting spinel structure by creating some defects at the lattice sites and make them suitable for magnetodielectric applications.In the present study,the nanoferrites of CuRE_(0.02)Fe_(1.98)O_4,where REs=Y~(3+),Yb~(3+),Gd~(3+),were prepared using one step sol-gel method.The prepared samples are copper ferrite(CFO),yttrium doped copper ferrite(Y-CFO),ytterbium doped copper ferrite(Yb-CFO) and gadolinium doped copper ferrite(Gd-CFO),respectively.The single-phase structure of all the REs doped nanoferrites was determined by X-ray diffraction(XRD) analysis.The porosity,agglomerations and grain size of the REs doped copper ferrite were examined using field emission scanning electron microscopy(FESEM) analysis.Fourier transform infrared spectroscopy(FTIR)elaborates the phase formation and environmental effects on the REs doped nanoparticles(NPs).The recorded room temperature M-H loops from a vibrating sample magnetometer(VSM) elucidate the magnetic properties of the REs doped spinel nanoferrites.The magnetic saturation(M_s) was calculated in the range of 23.08 to 51.78 emu/g.The calculated coercivity values(272.6 to 705.60 Oe) confirm the soft magnetic behavior of REs doped copper ferrites.Furthermore,the electromagnetic and dielectric properties were assessed using a Vector network analyzer(VNA) from 1 to 6 GHz.The permeability,permittivity,dielectric tangent loss and electric modulus of the REs doped spinel ferrites illustrate that the prepared NPs may be suitable for microwave and high frequency applications.     

济阳坳陷下古生界潜山油气藏特征及成藏模式

济阳坳陷下古生界潜山具有多样性、复杂性的特点，潜山差异性的形成演化、油气成藏主控因素和控藏模式不明确，严重制约了该区潜山油气勘探。在潜山分类的基础上，综合利用系统恢复、分类对比和典型解剖等方法，揭示了济阳坳陷下古生界不同类型潜山的形成演化过程和油气成藏主控因素差异性，分类建立了油气成藏模式。研究表明，济阳坳陷下古生界主要发育高位新盖侵蚀残丘潜山、中位古盖拉张断块潜山、中位新古盖拉张剪切断块潜山、中位中古盖挤压拉张断块潜山和低位古盖拉张滑脱断块潜山5种潜山类型。不同类型潜山的形成演化和油气成藏各具特色，其中，高位新盖侵蚀残丘潜山的发育受隆升、侵蚀作用控制，油气成藏主要受控于油源和盖层条件，表现为"单向供烃、砂体-不整合岩溶体联合输导、残丘控藏"的成藏模式；中位古盖拉张断块潜山的发育受掀斜、断裂作用控制，油气成藏主要受控于储集条件，表现为"单向供烃、顺向断层输导、反向断层控藏"的成藏模式；中位新古盖拉张剪切断块潜山的发育受反转、翘倾和走滑切割作用控制，油气成藏主要受控于输导条件，表现为"多源供烃、断溶体立体输导、断裂控藏"的成藏模式；中位中古盖挤压拉张断块潜山的形成受强烈挤压、拉张滑脱作用控制，油气成藏主要受控于储集条件，表现为"多源供烃、断缝体输导、断褶控藏"的成藏模式；低位古盖拉张滑脱断块潜山的形成受强烈拉张滑脱作用控制，油气成藏主要受控于输导条件，表现为"顶部供烃、断缝体输导、断裂控藏"的成藏模式。     

大学生创新能力培养模式的探索与实践

研究创新人才培养规律,探索和实践创新人才培养模式,是当前高校教育教学改革的一个重要方向。针对我校自动化专业立足国防、面向社会的人才培养特色,提出了以“创新意识、创新精神、创新技能”为核心的学生创新能力培养理念,通过构建创新能力培养“全链”模式、优化创新能力培养的“微生态”环境,取得了突出的成效。     

Effect of complexation of oxidised corn starch with mineral elements on physicochemical properties

The objective of this study was to determine the effect of complexation of oxidised starch with mineral elements on its physicochemical properties. Corn starch was oxidised with sodium hypochlorite and, afterwards, modified with ions of potassium, magnesium and iron. Thus, native and modified starches were analysed for: contents of mineral elements, colour parameters (L*a*b*), water binding capacity and solubility in water at temperature of 60 and 80 °C. Thermodynamic characteristics of gelatinisation by DSC, molecular weight distribution by GPC, intrinsic viscosity and pasting properties by RVA were studied. The efficiency of incorporation of metal ions into oxidised corn starch was about 30%, 20% and 20% for potassium, magnesium and iron ions, respectively. The complexation with potassium ions caused the greatest changes in the molecular weight distribution and the intrinsic viscosity of starches and viscosity of starch pastes. Only modification of starch with iron ions affected the colour parameters of the starch. Incorporation of metal ions into starch resulted also in changes in its water binding capacity and solubility in water.     

Finite-point method for efficient timing characterization of sequential elements

Timing characterization of sequential elements, such as latches and flip-flops, is one of the critical steps for timing closure in the pipelined design. Traditional characterization of setup and hold time constraints is computationally intensive, due to the demand on high accuracy in monitoring the operation failure. To improve the efficiency, this work proposes a finite-point based method for the characterization of setup and hold time constraints. The finite-point method identifies several critical data points in the non-linear curve of timing characteristics, and abstracts the essential setup/hold information from them. Moreover, compact models are derived for each point, further reducing the computation cost. The proposed method is general for all sequential elements in the standard cell library. It is comprehensively validated using benchmark circuits at 45 nm node. Experimental results demonstrate approximately 25× reduction in characterization time, with the prediction error in setup and hold time within 9% of FO₄ nominal delay, as compared to that of SPICE simulation results.     

湖北郧西西部地区金、锑矿成矿要素及成矿模式

湖北郧西西部地区金、锑矿位于秦岭泥盆系多金属成矿带的东南部镇旬成矿区的东侧,通过对郧西西部地区金、锑矿的成矿规律的综合分析和成矿要素的总结归纳,认为该区金、锑矿受构造、岩性控制。     

基于大数据的五年制高职护生在线学习行为要素研究

在线学习已逐渐成为高职院校一种重要学习形式,该领域也成为当前研究热点之一。对在线学习进行介绍,同时对大数据技术在在线学习平台中的应用进行分析,重点对五年制高职护生在线学习行为要素进行研究分析,为更好地开展在线学习评价提供参考,促进高职院校更好地开展在线学习,提高在线学习质量。     

Assessment of tracing element characteristics of F-type fly and bottom ash mixture

Presently, fly ash–water slurry is transported to ash disposal site at very low solid concentration of approximately 15–20% (by weight), resulting in huge water and energy wastage which leads to several environmental and health problem. The production of a large amount of the toxic metal elements in the ash disposal system of the thermal power plants can pose negative environmental effects on human health and on plants. In the present study, an attempt has been made to investigate the leaching characteristics of fly ash at higher concentrations. The bottom ash was taken as an additive in the proportion of 10, 20, and 30% (by weight) to enhance the leaching characteristics of fly ash. The solid concentration of fly ash suspension was taken in the range of 40 to 60% (by weight). The addition of additive helps to reduce the tracing metal concentration of fly ash. Leaching experiment data show that leachate concentration of all tracing elements present in fly ash reduced maximum with 20% addition of bottom ash (by weight). The present study helps to improve the ash disposal system of the thermal power plant and to minimize the environmental impact.     

基于敏感度分析的机床关键几何误差元素辨识与评定

为了正确识别和判定机床关键几何误差元素对机床精度设计的影响,以PCV-620立式加工中心为研究对象,采用多体系统理论建立机床空间误差模型,从而得到机床几何误差元素与机床精度之间的关联函数。对空间误差模型进行灵敏度分析,获得机床各运动方向的局部灵敏度系数,完成机床关键几何误差元素的初步辨识。以局部灵敏度系数为基础,提出一种与局部灵敏度系数和工作空间中任意位置处的几何误差元素值相关的全局灵敏度系数计算方法,将其作为机床关键几何误差元素的辨识和评定标准,分析得到PCV-620立式加工中心的关键几何误差元素包含3项定位误差、3项垂直度误差和5项直线度误差。